计算溶液所需的质量、体积或浓度。
这是演示店铺,请务下单付款,避免造成你的财物损失。
为了获得访问"阿拉丁铁蛋"实时聊天框的流畅支持体验,建议您使用Chrome浏览器或选择360浏览器极速模式(如何切换极速模式?),感谢您选择我们!
货号 (SKU) | 包装规格 | 是否现货 | 价格 | 数量 |
---|---|---|---|---|
D107997-25ml |
25ml | 现货 | | |
D107997-100ml |
100ml | 期货 | | |
D107997-500ml |
500ml | 期货 | | |
D107997-1L |
1L | 期货 | |
别名 | DIBAL-H;DIBAL |
---|---|
英文别名 | DIBAL-H;DIBAL |
规格或纯度 | 1.0 M in hexanes |
英文名称 | Diisobutylaluminum hydride |
应用 | Used in Pd-catalyzed reductive debromination of secondary alkyl bromides. O-Debenzylation and ring opening of perbenzylated furanosides. Convenient in situ generation of HZrCp2Cl from ZrCp2Cl2 and DIBAL-H. |
储存温度 | 充氩 |
运输条件 | 常规运输 |
产品介绍 |
Used in Pd-catalyzed reductive debromination of secondary alkyl bromides. O-Debenzylation and ring opening of perbenzylated furanosides. Convenient in situ generation of HZrCp2Cl from ZrCp2Cl2 and DIBAL-H. Used in Pd-catalyzed reductive debromination of secondary alkyl bromides. O-Debenzylation and ring opening of perbenzylated furanosides. Convenient in situ generation of HZrCp2Cl from ZrCp2Cl2 and DIBAL-H. |
EC号 | 214-729-9 |
---|---|
WGK Germany | 2 |
PubChem CID | 87569325 |
分子量 | 142.22 |
Beilstein号 | 4123663 |
溶解性 | Miscible with hydrocarbon solvents. |
---|---|
密度 | 0.701 |
敏感性 | 易吸潮;对空气敏感 |
闪点(℉) | 39.2 °F |
闪点(℃) | -18 °C |
沸点 | 116-118 °C |
一般危化品 | 一般危化品 |
---|---|
象形图 |
Health Hazard Corrosive Harmful Flammable |
信号词 | Danger |
危险声明 |
H373: Causes damage to organs through prolonged or repeated exposure H314: Causes severe skin burns and eye damage H225: Highly Flammable liquid and vapor H336: May cause drowsiness or dizziness H250: Catches fire spontaneously if exposed to air H304: May be fatal if swallowed and enters airways H361d: Suspected of damaging the unborn child H261: In contact with water releases flammable gas |
预防措施声明 | P261,P280,P231+P232,P422,P210,P222 |
WGK Germany | 2 |
个人防护装备 | Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter |
输入批号以搜索COA:
¥29.90
¥1,128.90
¥928.90
¥293.90
¥239.90
¥503.90
¥725.90
¥389.90
¥1,206.90
¥29.90
¥801.90
¥203.90
¥1,863.90
¥732.90
1. Z Y Liu,X R Wu. (1982-04-01) [The reduction of prostaglandin intermediate with diisobutylaluminium hydride].. Yao xue xue bao = Acta pharmaceutica Sinica, 17 ((4)): (296-298). [PMID:7136716] |
2. Y Kitade,K Hirota,Y Maki. (1992-01-01) Facile reductive cleavage of purine nucleosides to acyclonucleosides using diisobutylaluminium hydride (DIBAL): a new synthetic method for the preparation of 9-ribitylpurine derivatives.. Nucleic acids symposium series, ((27)(27)): (107-108). [PMID:1289780] |
3. K Hirota,Y Monguchi,M Sako,Y Kitade. (1995-01-01) Substitution effect of purine nucleosides on diisobutylaluminum hybride reduction.. Nucleic acids symposium series, ((34)): (15-16). [PMID:8841529] |
4. D J Kopecky,S D Rychnovsky. (2000-05-18) Improved procedure for the reductive acetylation of acyclic esters and a new synthesis of ethers.. The Journal of organic chemistry, 65 ((1)): (191-198). [PMID:10813915] |
5. J Marco-Contelles,J Ruiz-Caro. (2001-09-13) DIBALH mediated reduction of the acetal moiety on perhydrofuro[2,3-b]pyran derivatives.. Carbohydrate research, 335 ((1)): (63-70). [PMID:11553355] |
6. V Constantinou-Kokotou,V Magrioti,T Markidis,G Kokotos. (2001-10-19) Synthesis of enantiopure non-natural alpha-amino acids using tert-butyl (2S)-2-[bis-(tert-butoxycarbonyl)amino]-5-oxopentanoate as key-intermediate:the first synthesis of(S)-2-amino-oleic acid.. The journal of peptide research : official journal of the American Peptide Society, 58 ((4)): (325-331). [PMID:11606217] |
7. Kevin W Hunt,Paul A Grieco. (2002-02-14) Oxabicyclo[3.2.1]octenes in organic synthesis: direct ring opening of oxabicyclo[3.2.1] ring systems with diisobutylaluminum hydride and a silyl ketene acetal--synthesis of the chiral C(19)-C(26) and C(27)-C(32) fragments of Scytophycin C.. Organic letters, 4 ((2)): (245-248). [PMID:11796061] |
8. Thomas Lecourt,Alexandre Herault,Alan J Pearce,Matthieu Sollogoub,Pierre Sinaÿ. (2004-06-24) Triisobutylaluminium and diisobutylaluminium hydride as molecular scalpels: the regioselective stripping of perbenzylated sugars and cyclodextrins.. Chemistry (Weinheim an der Bergstrasse, Germany), 10 ((12)): (2960-2971). [PMID:15214078] |
9. Hideki Ishii,Sergei V Dzyuba,Koji Nakanishi. (2005-09-21) Lactone-free ginkgolides via regioselective DIBAL-H reduction.. Organic & biomolecular chemistry, 3 ((19)): (3471-3472). [PMID:16172680] |
10. Carl A Busacca,Ravinder Raju,Nelu Grinberg,Nizar Haddad,Paul James-Jones,Heewon Lee,Jon C Lorenz,Anjan Saha,Chris H Senanayake. (2008-01-17) Reduction of tertiary phosphine oxides with DIBAL-H.. The Journal of organic chemistry, 73 ((4)): (1524-1531). [PMID:18197688] |
11. Nobuo Tanaka,Izumi Ogawa,Shigeki Yoshigase,Junzo Nokami. (2008-08-23) Regioselective ring opening of benzylidene acetal protecting group(s) of hexopyranoside derivatives by DIBAL-H.. Carbohydrate research, 343 ((15)): (2675-2679). [PMID:18718576] |
12. Hidetsura Cho,Yusuke Iwama,Kenji Sugimoto,Seiji Mori,Hidetoshi Tokuyama. (2009-12-31) Regioselective synthesis of heterocycles containing nitrogen neighboring an aromatic ring by reductive ring expansion using diisobutylaluminum hydride and studies on the reaction mechanism.. The Journal of organic chemistry, 75 ((3)): (627-636). [PMID:20039606] |
13. Kenji Shirokane,Yusuke Kurosaki,Takaaki Sato,Noritaka Chida. (2010-07-31) A direct entry to substituted N-methoxyamines from N-methoxyamides via N-oxyiminium ions.. Angewandte Chemie (International ed. in English), 49 ((36)): (6369-6372). [PMID:20672260] |
14. Takashi Tomioka,Yuki Yabe,Tohru Takahashi,Tracy K Simmons. (2011-04-30) DIBAL-mediated reductive transformation of trans-dimethyl tartrate acetonide into ε-hydroxy α,β-unsaturated ester and its derivatives.. The Journal of organic chemistry, 76 ((11)): (4669-4674). [PMID:21526866] |
15. Ramprasad Ghosh,Ping Zhang,Aixia Wang,Chang-Chun Ling. (2011-10-19) Diisobutylaluminum hydride mediated regioselective O desilylations: access to multisubstituted cyclodextrins.. Angewandte Chemie (International ed. in English), 51 ((7)): (1548-1552). [PMID:22006644] |
16. Kenji Sugimoto. (2011-11-02) [Development of domino reactions based on skeletal rearrangement].. Yakugaku zasshi : Journal of the Pharmaceutical Society of Japan, 131 ((11)): (1563-1573). [PMID:22041694] |
17. Damien Webb,Timothy F Jamison. (2011-12-31) Diisobutylaluminum hydride reductions revitalized: a fast, robust, and selective continuous flow system for aldehyde synthesis.. Organic letters, 14 ((2)): (568-571). [PMID:22206502] |
18. Nora Heinrich,Anthony C Willis,Ian A Cade,Junming Ho,Michelle L Coote,Martin G Banwell. (2012-09-19) Reversible cyclopropane ring-cleavage reactions within etheno-bridged [4.3.1]propelladiene frameworks leading to aza- and oxa-[5.6.5.6]fenestratetraenes.. Chemistry (Weinheim an der Bergstrasse, Germany), 18 ((43)): (13585-13588). [PMID:22987604] |
19. Janclei P Coutinho,Gerardo F Barbero,Oreto F Avellán,A Garcés-Claver,Helena T Godoy,Miguel Palma,Carmelo G Barroso. (2015-01-27) Use of multivariate statistical techniques to optimize the separation of 17 capsinoids by ultra performance liquid chromatography using different columns.. Talanta, 134 (): (256-263). [PMID:25618665] |