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货号 (SKU) | 包装规格 | 是否现货 | 价格 | 数量 |
---|---|---|---|---|
L106746-100ml |
100ml |
现货 ![]() |
| |
L106746-500ml |
500ml |
现货 ![]() |
|
别名 | 双三甲基硅基胺基锂;LiHMDS |
---|---|
英文别名 | LiHMDS; Bis(trimethylsilyl)amine lithium salt; Lithium Hexamethyldisilazide; Hexamethyldisilazane Lithium Salt; 1,1,1,3,3,3-Hexamethyldisilazane lithium salt |
规格或纯度 | 1.0 M in toluene |
英文名称 | Lithium bis(trimethylsilyl)amide |
应用 | 非亲核性强碱,可用于形成烯醇的反应,烯醇酯立体专一克莱森重排反应,将醛转化为硅亚胺的反应,生成缩水甘油酸酯的反应,β内酰胺的反应,芳基烷基醚的选择性断裂反应。 |
储存温度 | 2-8°C储存,充氩 |
运输条件 | 冰袋运输 |
产品介绍 |
加水水解 。非亲核性强碱,可用于形成烯醇的反应,烯醇酯立体专一克莱森重排反应,将醛转化为硅亚胺的反应,生成缩水甘油酸酯的反应,β内酰胺的反应,芳基烷基醚的选择性断裂反应。 |
EC号 | 223-725-6 |
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IUPAC Name | lithium;bis(trimethylsilyl)azanide |
INCHI | InChI=1S/C6H18NSi2.Li/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1 |
InChi Key | YNESATAKKCNGOF-UHFFFAOYSA-N |
Canonical SMILES | [Li+].C[Si](C)(C)[N-][Si](C)(C)C |
WGK Germany | 3 |
PubChem CID | 2733832 |
分子量 | 167.32 |
Beilstein号 | 3567910 |
密度 | 0.86 |
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敏感性 | 对空气和湿度敏感 |
闪点(℉) | -23.8 °F |
闪点(℃) | -3℃ |
象形图 |
![]() Health Hazard ![]() Corrosive ![]() Harmful ![]() Flammable |
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信号词 | Danger |
危险声明 |
H373: Causes damage to organs through prolonged or repeated exposure H411: Toxic to aquatic life with long lasting effects H314: Causes severe skin burns and eye damage H225: Highly Flammable liquid and vapor H336: May cause drowsiness or dizziness H304: May be fatal if swallowed and enters airways H361f: Suspected of damaging fertility |
预防措施声明 | P261,P305+P351+P338,P273,P280,P301+P310,P210 |
WGK Germany | 3 |
个人防护装备 | Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US) |
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