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双(三甲基硅烷基)氨基锂

规格或纯度: 1.0 M in toluene
有货

库存信息

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库存信息

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货号 (SKU) 包装规格 是否现货 价格 数量
L106746-100ml
100ml 现货 Stock Image
L106746-500ml
500ml 现货 Stock Image

基本描述

别名 双三甲基硅基胺基锂;LiHMDS
英文别名 LiHMDS; Bis(trimethylsilyl)amine lithium salt; Lithium Hexamethyldisilazide; Hexamethyldisilazane Lithium Salt; 1,1,1,3,3,3-Hexamethyldisilazane lithium salt
规格或纯度 1.0 M in toluene
英文名称 Lithium bis(trimethylsilyl)amide
应用 非亲核性强碱,可用于形成烯醇的反应,烯醇酯立体专一克莱森重排反应,将醛转化为硅亚胺的反应,生成缩水甘油酸酯的反应,β内酰胺的反应,芳基烷基醚的选择性断裂反应。
储存温度 2-8°C储存,充氩
运输条件 冰袋运输
产品介绍

加水水解 。非亲核性强碱,可用于形成烯醇的反应,烯醇酯立体专一克莱森重排反应,将醛转化为硅亚胺的反应,生成缩水甘油酸酯的反应,β内酰胺的反应,芳基烷基醚的选择性断裂反应。


名称和标识符

EC号 223-725-6
IUPAC Name lithium;bis(trimethylsilyl)azanide
INCHI InChI=1S/C6H18NSi2.Li/c1-8(2,3)7-9(4,5)6;/h1-6H3;/q-1;+1
InChi Key YNESATAKKCNGOF-UHFFFAOYSA-N
Canonical SMILES [Li+].C[Si](C)(C)[N-][Si](C)(C)C
WGK Germany 3
PubChem CID 2733832
分子量 167.32
Beilstein号 3567910

化学和物理性质

密度 0.86
敏感性 对空气和湿度敏感
闪点(℉) -23.8 °F
闪点(℃) -3℃

安全和危险性(GHS)

象形图
ghs08

Health Hazard

ghs05

Corrosive

ghs07

Harmful

ghs02

Flammable

信号词 Danger
危险声明 H373: Causes damage to organs through prolonged or repeated exposure
H411: Toxic to aquatic life with long lasting effects
H314: Causes severe skin burns and eye damage
H225: Highly Flammable liquid and vapor
H336: May cause drowsiness or dizziness
H304: May be fatal if swallowed and enters airways
H361f: Suspected of damaging fertility
预防措施声明 P261,P305+P351+P338,P273,P280,P301+P310,P210
WGK Germany 3
个人防护装备 Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US)

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参考文献

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